Sandwich‐Structured Fluorinated Polyimide Aerogel/Paraffin Phase‐Change Composites Simultaneously Enables Gradient Thermal Protection and Electromagnetic Wave Transmission

. The presence of the nondirectional PI aerogel middle layer can effectively prevent against the leakage of paraffin from the upper layer to the surface of the composite. Through a rational integration of three functional layers, the developed sandwich-structured composite not only can provide gradient thermal protection for hot objects over a long period but also exhibits an excellent wave-transparent capability to establish communication between two electromagnetically shielded electronic devices. With such prominent thermal insulation and wave-transparent functions, the sandwich-structured composite exhibits great potential for specific applications in aircraft, spacecraft, radar systems, and satellite communication.