The Synthesis of a Covalent Organic Framework from Thiophene Armed Triazine and EDOT and Its Application as Anode Material in Lithium-Ion Battery

材料科学 三嗪 阳极 共价键 电化学 噻吩 复合数 锂(药物) Stille反应 氧化还原 化学工程 高分子化学 聚合物 有机化学 电极 复合材料 化学 物理化学 冶金 内分泌学 工程类 医学
作者
Shuang Chen,Shukun Wang,Xin Xue,Jinsheng Zhao,Hongmei Du
出处
期刊:Polymers [MDPI AG]
卷期号:13 (19): 3300-3300 被引量:9
标识
DOI:10.3390/polym13193300
摘要

As a class of redox active materials with some preferable properties, including rigid structure, insoluble characters, and large amounts of nitrogen atoms, covalent triazine frameworks (CTFs) have been frequently adopted as electrode materials in Lithium-ion batteries (LIBs). Herein, a triazine-based covalent organic framework employing 3,4-ethylenedioxythiophene (EDOT) as the bridging unit is synthesized by the presence of carbon powder through Stille coupling reaction. The carbon powder was added in an in-situ manner to overcome the low intrinsic conductivity of the polymer, which led to the formation of the polymer@C composite (PTT-O@C, PTT-O is a type of CTFs). The composite material is then employed in LIBs as anode material. The designed polymer shows a narrow band gap of 1.84 eV, proving the effectiveness of the nitrogen-enriched triazine unit in reducing the band gap of the resultant polymers. The CV results showed that the redox potential of the composite (vs. Li/Li+) is around 1.0 V, which makes it suitable to be used as the anode material in lithium-ion batteries. The composite material could exhibit the stable specific capacity of 645 mAh/g at 100 mA/g and 435 mAh/g at 500 mA/g, respectively, much higher than the pure carbon materials, indicating the good reversibility of the material. This work provides some additional information on electrochemical performance of the triazine and EDOT based CTFs, which is helpful for developing a deep understanding of the structure–performance correlations of the CTFs as anode materials.
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