Removal of emulsified oil from water by using recyclable chitosan based covalently bonded composite magnetic flocculant: Performance and mechanism

In this work, a novel recyclable covalently bonded magnetic flocculant (FS-MC) was successfully prepared by combining chitosan-based modified polymers (MCS) with Fe3O4@SiO2 through a silane coupling agent. The covalent bond Fe–O–Si–O–C and the core–shell structure of FS-MC were confirmed through several characterization methods. The emulsified oily wastewater flocculation performance and mechanism by using FS-MC were evaluated and studied. Results showed that 94.47%, 93.95%, and 92.98% of emulsified oil could be removed by using FS-MC1, FS-MC2 and FS-MC3 at dosages of 2.0, 2.5, and 2.0 mg/L, respectively. Furthermore, FS-MC exhibited an excellent behavior on the removal of organic compounds with molecular weight > 10 kDa, including long chain alkanes, cycloalkanes, and aromatic hydrocarbon compounds. In addition, triple-phase separation of oil, water and flocculants was achieved by using magnetic FS-MC. Due to the introduction of cationic and hydrophobic groups in FS-MC, charge neutralization, compression double electric-layer action, hydrophobic interaction, interfacial adsorption bridging and sweep-flocculation synergistically contributed and enhanced the removal of emulsified oil. Recycling experiments also showed that no obvious decrease of oil removal rate was observed by using magnetic FS-MC flocculants in five cycles.