Visible-light-driven α-hydroxylation of β-dicarbonyl compounds mediated by NaI/NPh3 or NaI/PPh3 in water
化学
羟基化
药物化学
放射化学
光化学
核化学
有机化学
酶
作者
Yan Wang,Zhongjie Wang,Hui Luo,Guohui Wang,Zhendong Shi,Yinfeng Ma,Jianglong Wu,Dianjun Li,Jinhui Yang
出处
期刊:Organic chemistry frontiers [The Royal Society of Chemistry] 日期:2024-01-01卷期号:11 (19): 5524-5531
标识
DOI:10.1039/d4qo01169d
摘要
A mild and efficient light-mediated CH-hydroxylation of carbonyl compounds with water in the aqueous phase has been developed. Most attractively, NaI-NPh 3 was initially employed as an intermediate for photovoltaic conversion and electron transfer.