Cu-MOF/Pd derived oxide nanoparticles based carbon composite - An innovative electrochemical sensing platform for Bisphenol A

检出限 双酚A 电化学 材料科学 安培法 碳化 微分脉冲伏安法 电化学气体传感器 双酚S 阳极 化学工程 碳纤维 循环伏安法 电极 复合数 化学 色谱法 复合材料 扫描电子显微镜 物理化学 环氧树脂 工程类
作者
Veeramuthu Saravanakumar,Venkatachalam Rajagopal,Karthik Narayanan,Noel Nesakumar,Murugavel Kathiresan,V. Suryanarayanan,Sambandam Anandan
出处
期刊:Journal of Alloys and Compounds [Elsevier]
卷期号:963: 171216-171216 被引量:11
标识
DOI:10.1016/j.jallcom.2023.171216
摘要

Bisphenol A (BPA), an endocrine disrupting chemical, had been used worldwide as a raw material in water bottles and food packages. It leaches into food products and water sources and hence, it should be monitored effectively. Herein, an electrochemical sensing platform based on Cu-MOF@Pd-500 modified glassy carbon (GC) electrode was fabricated for the sensing of BPA. The material was synthesized by a simple solvothermal method, carbonized at 500 ⁰C, and characterized by various surface analytical techniques. Cyclic voltammetric (CV) analysis reveals that the Cu-MOF@Pd-500 modified GCE exhibits 1.5 folds hike in peak current and a considerable shift in peak potential towards the anodic side when compared to Cu-MOF@ 500, suggesting the higher electrocatalytic activity of the former than that of the later. The electrochemical oxidation of BPA provides an irreversible diffusion-controlled process involving two electrons and two protons. Differential pulse voltammetric (DPV) analysis reveals that the constructed sensor material provides a linear response over BPA concentration of 1 − 150 µM with a low detection limit (LOD) of 0.06 µM, (S/N = 3) and amperometric studies deliver a linear range of 1–22 µM with a LOD of 0.025 µM in 0.1 M PBS at a pH 7.0. Additionally, the Cu-MOF@Pd-500 delivers good repeatability, stability, and anti-interference capabilities. The results obtained also support the effectiveness of Cu-MOF@Pd-500 for quantifying and identifying BPA in real sample analysis (plastic water bottles) with an average recovery of the ratio of 101.93 having a relative standard deviation (RSD) of 0.42%.
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