区域选择性
烯烃
艾伦
模块化设计
化学
催化作用
组合化学
转化(遗传学)
有机化学
计算机科学
程序设计语言
生物化学
基因
作者
Ivan Keng Wee On,Ye Zhu
出处
期刊:Chem catalysis
[Elsevier]
日期:2023-04-01
卷期号:3 (4): 100604-100604
标识
DOI:10.1016/j.checat.2023.100604
摘要
In this issue of Chem Catalysis, Zhu et al. developed a photocatalytic 1,2-allenylfunctionalization of alkenes—a transformation previously unattainable because of the challenging regioselectivity control. Employing α-sulfonylbromoallenes as the allenyl radical precursor, this method readily assembles a plethora of highly functionalized allenes from low-cost feedstock under mild conditions.
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