羟醛反应
薗头偶联反应
偶联反应
化学
维蒂希反应
磷化氢
级联
有机合成
分子
超声波传感器
组合化学
有机化学
钯
催化作用
物理
色谱法
声学
作者
Rodrigo Cella,Hélio A. Stefani
标识
DOI:10.1002/9781119288152.ch14
摘要
The most modern ultrasonic devices rely on transducers, which are composed of piezoelectric materials. Cavitation induces very high local temperatures and pressures inside the bubbles, leading to a turbulent flow of the liquid and enhanced mass transfer. Aldol/condensations reactions are an important class of organic reaction once they are extremely used in the formation of the C-C bond. A one-pot methodology to synthesize 4-styryl biphenyls 133 units was developed using a cascade reaction involving Wittig-Suzuki in a phosphine-free system. The Diels-Alder reactions importance as a synthetic tool in organic chemistry is unquestionable in the creation of cyclic molecules and heterocyclic. The importance of heterocycles in many fields of science can hardly be overemphasized and justifies a long lasting effort to work out new synthetic protocols for their production. Sonogashira cross-coupling reaction is the best reaction to perform alkynylation of aryl or vinyl halides.
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