Waterborne superamphiphobic coatings with network structure for enhancing mechanical durability

Superamphiphobic coatings may significantly change the wettability of a substrate, and so are attractive for applications in aero/marine engineering, biotechnology, and heat transfer. However, the coatings are caught in a double bind when their durability is considered, as they are vulnerable to mechanical abrasion. Meanwhile, the wide use of organic solvents for preparing the coatings generates environmental pollution. Here, we present a waterborne superamphiphobic coating through one-step spraying that repels a wide range of liquids. By tailoring the repellence of the nano-silica to waterborne resin, a network structure is constructed to protect the embedded nano-silica from damage. Thus, the coatings are durable against 725 cycles of friction tester abrasion under a load of 250 g, showing a significant improvement in the mechanical durability by 3-25 times. Moreover, our coating also shows excellent comprehensive durability, including resistance to oil-flow erosion, falling sand impact, chemical attack, thermal treatment, etc. This strategy can be introduced to various waterborne resins, demonstrating its universality, and may offer a new insight to design sustainable superamphiphobic coatings for long-term practical applications.