化学
全合成
区域选择性
仿生合成
选择性
硅烷化
产量(工程)
组合化学
立体化学
有机化学
催化作用
冶金
材料科学
作者
Xiangdong Hu,Tao Yu,Xin Shu,Ke‐Wu Yang
出处
期刊:Synlett
[Georg Thieme Verlag KG]
日期:2018-06-18
卷期号:29 (12): 1617-1621
被引量:2
标识
DOI:10.1055/s-0037-1610178
摘要
A biomimetic total synthesis of scabellone B is described. Through sequential regioselective introduction of a geranyl group by means of silyl protection, oxidative dimerization, and biomimetic oxo-6π electrocyclization with good cyclization selectivity, a biomimetic approach to scabellone B was achieved in five steps and 32% overall yield.
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