煤
自燃
传热
热扩散率
燃烧
废物管理
放热反应
化学
环境科学
热力学
工程类
物理
有机化学
作者
Yuanbo Zhang,Yutao Zhang,Xueqiang Shi,Shangming Liu,Shu Pan,Shangwen Xia
标识
DOI:10.1016/j.scitotenv.2022.157072
摘要
To explore the thermal behavior and hazard during the spontaneous combustion fires (SCFs) of coal and coal gangue (CG), the characteristics of heat release and thermal transfer during the SCFs of coal and CG were tested. The results indicate that coal contains more combustibles and aromatic hydrocarbons, while CG possesses higher contents of ash and inorganic silicate. Coal has a stronger heat release capacity, while CG owns a smaller specific heat capacity, a larger thermal diffusivity and a greater thermal conductivity. Thus, CG performs better with respect to heat transfer. The apparent activation energy of coal is larger in the endothermic stage, whereas that of CG is more notable in the exothermic stage. Based on heat release and heat transfer performance, hazardous zones during the SCFs of coal and CG were identified, and the combustion growth index was established to quantify the hazard of SCF disasters. The results show that the hazard is determined by both heat release and thermal transfer capacities. Coal or CG with a combustible component of 31.3 %, which not only releases massive heat but also transfers heat quickly, corresponds to the most considerable hazard of SCF disasters.
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