材料科学
X射线光电子能谱
傅里叶变换红外光谱
荧光光谱法
荧光
猝灭(荧光)
纳米颗粒
金属有机骨架
检出限
水溶液
水溶液中的金属离子
铜
光致发光
光谱学
分析化学(期刊)
化学工程
化学
纳米技术
金属
物理化学
吸附
有机化学
光电子学
工程类
物理
量子力学
冶金
色谱法
作者
Harisankar Asadevi,Preethi Prasannakumaran Nair Chandrika Kumari,Rejani Padmavati Amma,Shahana Abdul Khadar,Saranya Charivumvasathu Sasi,Resmi Raghunandan
出处
期刊:ACS omega
[American Chemical Society]
日期:2022-04-07
卷期号:7 (15): 13031-13041
被引量:27
标识
DOI:10.1021/acsomega.2c00416
摘要
Recently, the synthesis, characterization, and structural evaluation of metal–organic framework (MOF) nanocomposites gain more attention due to the versatility in their applications. In the present work, the fluorescent active ZnO@MOF-5 composite was synthesized by encapsulating ZnO nanoparticles into the zinc terephthalate metal–organic framework (MOF-5). ZnO nanoparticles were prepared by a green method using the leaf extract of Annona muricata. Incorporation of ZnO nanoparticles onto the framework structure (ZnO@MOF-5) was done by a solvothermal method. The new composite material was characterized by Fourier transform infrared spectroscopy, Powder X-ray diffraction, Ultraviolet–visible spectroscopy, Transmission Electron Microscopy, X-ray photoelectron spectroscopy, Brunauer–Emmett–Teller analysis, Dynamic light scattering, Thermogravimetry-Differential Thermal analysis, and Photoluminescence spectroscopy. The material displayed blue fluorescence with a peak at 402 nm upon excitation at 282.46 nm. ZnO@MOF-5 showed a good fluorescence sensing efficiency toward the detection as well as probing of Cu(II) ions in aqueous solution. Sensing experiments performed revealed that as the concentration of copper ions in the solution increases, the quenching efficiency of the composite also increases. A quenching efficiency of 96.20% was achieved on reaching a concentration of 5 μM. The limit of detection for the sensing of Cu2+ ions was calculated to be 0.185 μM.
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