化学
蒸汽压
一致性(知识库)
热力学
分数(化学)
摩尔分数
再现性
物理化学
有机化学
色谱法
物理
几何学
数学
作者
M. Palczewska-Tulińska,Paweł Oracz
摘要
Vapor−liquid equilibrium data were measured using the Świȩtosławski ebulliometric still in the binary 2-methylcyclohexanol + 2-methylcyclohexyl ethanoate system at a constant pressure of (101.325 ± 0.070) kPa. The saturated vapor pressures were also measured for samples of mole fraction purity of 99.97 % 2-methylcyclohexanol and 99.98 % 2-methylcyclohexyl ethanoate over wide temperature ranges by comparative ebulliometry. The experimental data were correlated using the maximum-likelihood method, and overall measures of data reproducibility are given. The results are compared with literature data. VLE experimental data were tested for thermodynamic consistency by means of several different consistency tests and were demonstrated to be consistent.
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