Total Syntheses of Indole Terpenoids (−)-Lyngbyatoxin, (−)-Teleocidin A2, and (−)-7-Geranylindolactam V

A regiodivergent palladium-catalyzed Suzuki-Miyaura reaction has been successfully implemented to synthesize (-)-lyngbyatoxin, (-)-teleocidin A2, and (-)-7-geranylindolactam V. This ligand-controlled cross-coupling strategy allowed for the direct preparation of these natural products from a single advanced synthetic intermediate, providing the shortest reported route to each compound. Subsequent