海水
析氧
电化学
硼
催化作用
分解水
循环伏安法
化学
无机化学
电解质
人工海水
化学工程
材料科学
电极
海洋学
有机化学
地质学
工程类
物理化学
光催化
作者
Zekun Wang,Xueqing Niu,Lin Ye,Xiaoyu Wang,Chao Wang,Yong‐Hong Wen,Lingbo Zong,Lei Wang,Hongtao Gao,Xingwei Li,Tianrong Zhan
标识
DOI:10.1016/j.jcis.2024.04.198
摘要
Transition metal-based electrocatalysts generally take place surface reconstruction in alkaline conditions, but little is known about how to improve the reconstruction to a highly active oxyhydroxide surface for an efficient and stable oxygen evolution reaction (OER). Herein, we develop a strategy to accelerate surface reconstruction by combining boron modification and cyclic voltammetry (CV) activation. Density functional theory calculations and in-situ/ex-situ characterizations indicate that both B-doping and electrochemical activation can reduce the energy barrier and contribute to the surface evolution into highly active oxyhydroxides. The formed oxyhydroxide active phase can tune the electronic configuration and boost the OER process. The reconstructed catalyst of CV-B-NiFe-LDH displays excellent alkaline OER performance in freshwater, simulated seawater, and natural seawater with low overpotentials at 100 mA cm−2 (η100: 219, 236, and 255 mV, respectively) and good durability. This catalyst also presents outstanding Cl− corrosion resistance in alkalized seawater electrolytes. The CV-B-NiFe-LDH||Pt/C electrolyzer reveals prominent performance for alkalized freshwater/seawater splitting. This study provides a guideline for developing advanced OER electrocatalysts by promoting surface reconstruction.
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