过硫酸盐
降级(电信)
水溶液
三氯乙烯
化学
纳米颗粒
硫化铁
傅里叶变换红外光谱
过硫酸钠
环境修复
硫化物
催化作用
化学工程
核化学
材料科学
环境化学
纳米技术
硫黄
污染
有机化学
电信
生态学
生物
计算机科学
工程类
作者
Mudassir Habib,Tehreem Ayaz,Meesam Ali,Zhiqiang Xu,Zheng-Yuan Zhou,Siraj Ullah,Shuguang Lyu
标识
DOI:10.1016/j.jwpe.2024.104922
摘要
Trichloroethylene (TCE) is known for its carcinogenic properties and limited environmental degradation. Therefore, TCE degradation was carried out using a catalyzed system, i.e., an advanced oxidation process (AOP) for an aqueous solution. This study focuses on activating sodium persulfate (PS) by laboratory-synthesized iron sulfide nanoparticles (FeS-NPs) with a particle size of 115.17 nm for enhanced TCE degradation. Field emission scanning electron microscope (FESEM), transmission electron microscopy (TEM), X-ray diffractometry (XRD), Fourier transform infrared spectroscopy (FTIR), and Brunauer-Emmett-Teller (BET) analyses were employed to investigate physio-chemical properties and surface morphologies of synthesized FeS-NPs catalyst. PS/FeS-NPs exhibited outstanding performance, achieving a remarkable degradation (99.07 %) of TCE in 60 min of reaction time, surpassing the degradation demonstrated by commercially available PS/FeS (25 %). The dominant involvement of Fe transformation and SO4•ˉ, OH•, and 1O2 radicals in TCE degradation was validated through scavenging and electron paramagnetic resonance (EPR) investigation. Moreover, the PS/FeS-NPs system was found efficient (97⁓99 %) in both acidic and basic solutions, although it is noteworthy that highly basic (pH 11) mediums may impact the degradation efficiency (13.8 %). Recycling and stability experiments revealed significant efficiency of the PS/FeS-NPs system during the second run (90.02 %) and third run (68.25 %). These core revelations validate the efficiency of FeS-NPs in TCE degradation in an aqueous solution. Conclusively, the PS/FeS-NPs system encouraged TCE degradation outcomes, depicting strong potential for prolonged benefits in the remediation of TCE-polluted water.
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