材料科学
自愈水凝胶
丙烯酸酯
聚合物
丙烯酰胺
复合材料
溶剂
极限抗拉强度
多孔性
拉伸试验
聚丙烯酸钠
肿胀 的
化学工程
高分子化学
化学
共聚物
有机化学
原材料
工程类
作者
Beatrice Ehrke,Jan Erfkamp,Thomas Wallmersperger
标识
DOI:10.1177/1045389x211014571
摘要
Stimuli-responsive hydrogels consist of a porous 3D framework that is saturated with solvent. Immersed in a solution bath, these gels can exhibit an enormous volume change due to absorption or release of solution. Depending on the type of gel, this effect can be generated for example by variation of the ion concentration in the surrounding solution bath or by an applied electrical field. The mechanical behavior of these polymers is influenced not only by the solid-state skeleton, but also by the interacting fluid. Thus, a visco-elastic behavior can be observed on the macroscopic scale. Based on the specific properties of the polymer gel and the interaction of the different phases, the determination of the mechanical properties of this material turns out to be non-trivial. In the present work, the mechanical behavior of a poly(acrylamide-co-sodium acrylate) hydrogel in the fully swollen state is investigated by a newly developed tensile test and for longtime investigations by a creep test. For this purpose, two newly developed different experimental setups based on digital image correlation are used.
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