螺旋烯
光致发光
分子
光电子学
吸收(声学)
化学
发光
化学物理
材料科学
有机化学
复合材料
作者
Jikun Li,Xing-Yu Chen,Yunlong Guo,Xinchang Wang,Andrew C.‐H. Sue,Xiaoyu Cao,Xiaoye Wang
标识
DOI:10.33774/chemrxiv-2021-rmsq8
摘要
The development of helicene molecules with significant chiroptical responses covering a broad range of the visible spectrum is highly desirable for chiral optoelectronic applications; however, their absorption dissymmetry factors (gabs) have been mostly lower than 0.01. In this work, we report unprecedented B,N-embedded double hetero[7]helicenes with nonbonded B and N atoms, which exhibit excellent chiroptical properties, such as strong chiroptical activities from 300 to 700 nm, record high gabs up to 0.033 in the visible spectral range, and tunable circularly polarized luminescence (CPL) from red to near-infrared regions (600 ~ 800 nm) with high photoluminescence quantum yields (PLQYs) up to 100%. As revealed by theoretical analyses, the high gabs values are related to the separate molecular orbital distributions owing to the incorporation of nonbonded B and N atoms. The new type of B,N-embedded double heterohelicenes opens up an appealing avenue to the future exploitation of high-performance chiroptical materials.
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