化学
层状双氢氧化物
离子交换
无机化学
硫酸盐
降水
碱金属
定性无机分析
碱土金属
钾
锂(药物)
钠
硫酸钾
离子
氢氧化物
有机化学
气象学
内分泌学
物理
医学
作者
Anne Raquel Sotiles,Loana Mara Baika,Marco Tadeu Grassi,Fernando Wypych
摘要
Layered double hydroxides (LDHs) with similar compositions to the minerals shigaite, natroglaucocerinite, and motukoreaite were synthesized by co-precipitation with increasing pH and characterized by several instrumental techniques. These minerals have previously been described to occur only with sodium and sulfate (Na(H2O)6)[M+26Al3(OH)18(SO4)2]·6H2O (M2+ = Mn, Mg, and Zn). These phases were synthesized successfully along with others containing lithium and potassium. Cation exchange reactions were performed in the presence of alkaline metal sulfates, and for the first time several instrumental techniques were employed to show that the cations can be totally exchanged without removing the intercalated sulfate anions. This class of compounds, traditionally considered to be anion exchangers, can also be considered cation exchangers, which opens new avenues for future scientific and industrial applications.
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