To address the challenge of high-temperature microwave absorbing materials (MAM) for the hot-end components of aircraft, SiC enhanced ZrB2–Al2O3 (ZSA) ceramics are prepared by pressureless sintering. In ZSA ceramics, ZrB2 and SiC are the absorbers and Al2O3 is the matrix. The effect of the content of SiC on microwave absorption properties for the ZSA ceramics are studied. The results show that the addition of SiC enhances the MA properties and high-temperature stability of ZrB2–Al2O3 ceramics. Ceramics with an effective absorption bandwidth (EAB) of 3.9 GHz at a thickness of 1.56 mm; and a minimum reflection loss (RLmin) of −15 dB is obtained. After treatment at 1000 °C for 20 h in an air atmosphere, the EAB reduces to 3.5 GHz at the thickness of 1.56 mm, however, RLmin reaches −21 dB. ZSA ceramics consume microwaves through effect including interfacial polarization relaxation, conductive loss and multiple reflection loss. This work is expected to provide new ideas for the design and development of high-temperature microwave absorbing materials.