化学
起爆
亚硝酸钠
戒指(化学)
三嗪
组合化学
有机化学
高分子化学
爆炸物
作者
Zhiwei Zeng,Chunhui Chen,Xuran Xu,Yuji Liu,Wei Huang,Yongxing Tang
标识
DOI:10.1021/acs.joc.4c00821
摘要
Two 6,5,6-fused 1,2,3-triazine-3-oxides (4 and 6) were designed and synthesized via the reaction of o-aminoamidoximes with sodium nitrite. In addition, the ring-opening products (5, 7, and 8) derived from 1,2,3-triazine-3-oxides were isolated and characterized. A comprehensive exploration of the reaction mechanism governing the ring-opening process was performed through a combination of theoretical and experimental studies. Notably, compound 4 exhibited commendable detonation properties and low sensitivity, demonstrating its promising potential as an energetic material.
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