Microplastics in the environment: Occurrence, perils, and eradication

Microplastics (MPs) with sizes < 5 mm are found in various compositions, shapes, morphologies, and textures that are the major sources of environmental pollution. The fraction of MPs in total weight of plastic accumulation around the world is predicted to be 13.2% by 2060. These micron-sized MPs are hazardous to marine species, birds, animals, soil creatures and humans due to their occurrence in air, water, soil, indoor dust and food items. The present review covers discussions on the damaging effects of MPs on the environment and their removal techniques including biodegradation, adsorption, catalytic, photocatalytic degradation, coagulation, filtration and electro-coagulation. The main techniques used to analyze the structural and surface changes such as cracks, holes and erosion post the degradation processes are FTIR and SEM analysis. In addition, reduction in plastic molecular weight by the microbes implies disintegration of MPs. Adsorptive removal by the magnetic adsorbent promises complete elimination while the biodegradable catalysts could remove 70-100% of MPs. Catalytic degradation via advanced oxidation assisted by SO4•- or OH• radicals generated by peroxymonosulfate or sodium sulfate are also adequately covered in addition to photocatalysis. The chemical methods such as sol-gel, agglomeration, and coagulation in conjunction with other physical methods are discussed concerning the drinking water/wastewater/sludge treatments. The efficacy, merits and demerits of the currently used removal approaches are reviewed that will be helpful in developing more sophisticated technologies for the complete mitigation of MPs from the environment.