聚苯胺
电合成
生物相容性
材料科学
纳米技术
电极
电化学
纳米颗粒
表面改性
小型化
电化学气体传感器
生物电子学
检出限
银纳米粒子
纳米线
生物传感器
化学工程
化学
聚合物
复合材料
聚合
色谱法
物理化学
工程类
冶金
作者
Luyen Thi Tran,Hoang Vinh Tran,Đặng Thị Minh Huệ,Chinh Dang Huynh,Mai Anh Tuan
出处
期刊:Journal of The Electrochemical Society
[The Electrochemical Society]
日期:2020-05-04
卷期号:167 (8): 087508-087508
被引量:22
标识
DOI:10.1149/1945-7111/ab8fdb
摘要
In this work, silver nanoparticles decorated onto polyaniline nanowires were synthesized site-specifically onto Pt working electrodes (with only 0.8 mm2 area) using a novel, rapid, and effective electrochemical procedure: electropolymerization of PANi NWs and electrodeposition of AgNPs. The complementary properties of PANi NWs and AgNPs were obtained, including high surface area, high electrochemical activity, high biocompatibility, high chemical stability and good adhesion with the electrode surface. Obtained results showed advantages of the electrosynthesis method compared to traditional methods, which have difficulties in binding between modifying materials with electrode surfaces. The sensor surface modification with the PANi NWs/AgNPs material facilitated the probe DNA immobilization and improved the electrochemical signal of the DNA sensors. The detection limit of the sensors was 2.80 × 10−15 M. The DNA sensors exhibited advantages including direct detection, high sensitivity, good specificity, and potential miniaturization for development of lab-on-a-chip systems.
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