丙烯
丙烷
脱氢
氮化硼
选择性
催化作用
放热反应
烯烃
化学
硼
从头算
氮化物
六方氮化硼
光化学
无机化学
材料科学
有机化学
纳米技术
石墨烯
图层(电子)
作者
Joseph T. Grant,Carlos A. Carrero,Florian Göeltl,Juan M. Venegas,Philipp Müller,Samuel P. Burt,Sarah E. Specht,William P. McDermott,Alessandro Chieregato,Ive Hermans
出处
期刊:Science
[American Association for the Advancement of Science (AAAS)]
日期:2016-12-02
卷期号:354 (6319): 1570-1573
被引量:584
标识
DOI:10.1126/science.aaf7885
摘要
Boron nitride catalysis Propene is one of the highest-volume organic chemicals produced. Propene has mainly been made from naphtha, but changes in the global supply chain are creating shortages. Direct conversion from propane, a component of natural gas, via reaction with oxygen is an attractive alternative, but existing approaches produce a large fraction of unwanted CO and CO 2 . Grant et al. report that boron nitride, normally an unreactive material, has high selectivity to catalyze the production of propene (77%) and ethene (13%). Science , this issue p. 1570
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