锑
催化作用
氧气
吸附
氧还原反应
氧化锑
块(置换群论)
化学
光化学
还原(数学)
无机化学
电极
电催化剂
选择性催化还原
化学工程
材料科学
电化学
物理化学
有机化学
氧化物
数学
工程类
几何学
作者
Tongzhou Wang,Xuejie Cao,Hongye Qin,Long Shang,Siyu Zheng,Fang Fang,Lifang Jiao
标识
DOI:10.1002/anie.202108599
摘要
A p-block atomically dispersed antimony with Sb−N4 configuration has been developed and used as highly efficient oxygen reduction reaction (ORR) electrocatalyst. The excellent ORR activity is credited to the p orbital interaction between Sb cation and O2, which facilitates the charge transfer and generates appropriate adsorption strength for oxygen intermediates, lowering the energy barrier and modulating the rate-determining step.
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