材料科学
电解质
锌
铟
电极
卤化物
氧化物
化学工程
无机化学
光电子学
化学
冶金
工程类
物理化学
作者
Desmond C. Madu,Micah V. Lilo,Andrew Thompson,Hanqing Pan,Michael D. McGehee,Christopher J. Barile
标识
DOI:10.1021/acsami.2c14893
摘要
Reversible metal electrodeposition (RME) is an emerging and promising method for designing dynamic windows with electrically controllable transmission, excellent color neutrality, and wide dynamic range. Zn is a viable option for metal-based dynamic windows due to its fast switching kinetics and reversibility despite its very negative deposition voltage. In this manuscript, we study the effect of the supporting electrolyte anions for Zn electrodeposition on transparent tin-doped indium oxide. Through systematic additions or removal of components of the electrolytes, we are able to establish a link between the anions and the effectiveness of Zn RME. This insight allows us to design practical two-electrode 25 cm2 Zn dynamic windows that switch to <1% within 20 s. Lastly, we demonstrate that the accumulation of Zn(OH)2 species on the working electrode degrades the optical contrast of Zn windows during long-term cycling. However, the elimination of these species through acid immersion allows the windows to cycle at least 500 times. Reversible Zn electrodeposition in the presence of a polyethylene glycol additive further improves the cycle life to greater than 1000 cycles. Taken together, these studies highlight important design principles for the construction of robust dynamic windows based on Zn RME.
科研通智能强力驱动
Strongly Powered by AbleSci AI