二乙烯三胺
三乙烯四胺
吸附
介孔二氧化硅
热重分析
介孔材料
聚乙烯亚胺
核化学
化学
傅里叶变换红外光谱
解吸
相对湿度
乙二胺
物理吸附
材料科学
化学工程
无机化学
有机化学
催化作用
工程类
物理
基因
热力学
生物化学
转染
作者
Rajesh Kumar,Mahuya Bandyopadhyay,Madhu Pandey,Nao Tsunoji
标识
DOI:10.1016/j.micromeso.2022.111956
摘要
Various amine-impregnated mesoporous silica adsorbents were prepared for a comparative study of 400 ppm CO2 adsorption at room temperature (25 or 30 °C) under dry and 60% relative humidity conditions. Five types of amines–polyethylenimine (PEI), tetraethylenepentamine (TEPA), triethylenetetramine (TETA), diethylenetriamine (DETA), and ethylenediamine (EDA)–and three types of mesoporous silica with different pore structures (SBA-15, MCM-41, and MCM-48) were used. The amine loading amount was also optimized according to the CO2 adsorption results obtained using a thermogravimetric analyzer under dry conditions. SBA-15 samples with 50–60 wt% loadings of TEPA and TETA showed a relatively high adsorption capacity of approximately 2 mmol g−1. The adsorption capacities of EDA and DETA loaded samples were less than 0.5 mmol g−1. The PEI impregnated SBA-15 exhibited relatively high CO2 adsorption rate (0.058 mmol g−1 min−1). X-ray diffraction, Fourier transform infrared spectroscopy, N2 adsorption/desorption, and scanning electron microscopy revealed that the amines filled the mesopores of the sample. The amines also covered the outer surface of the mesoporous silica with narrow pore sizes (MCM-41 and MCM48). In humid conditions, SBA-15 with 50 wt% loading of PEI, TEPA, and TETA showed an adsorption capacity of 2.16 mmol g−1, 2.12 mmol g−1, and 1.80 mmol g−1, respectively. An enhanced capacity was observed under humid conditions, especially for the PEI-loaded samples. During the cyclic adsorption test, PEI-and TEPA-impregnated SBA-15 exhibited superior cycling stability compared to the sample with TETA, where the material retained a capacity of approximately 2 mmol g−1 over 10 cycles.
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