偶氮苯
马朗戈尼效应
聚苯乙烯
聚合物
材料科学
无定形固体
图层(电子)
表面张力
辐照
化学工程
纳米技术
复合材料
化学
有机化学
核物理学
工程类
物理
量子力学
作者
Issei Kitamura,Mitsuo Hara,Shusaku Nagano,Takahiro Seki
标识
DOI:10.1080/15421406.2021.1946966
摘要
Surface relief gratings (SRGs) are widely investigated in azobenzene-containing polymer films. We have recently demonstrated that a photoresponsive azobenzene layer existing only at the surface of a non-photoresponsive liquid crystalline polymer film can induce mass migration by patterned UV light irradiation, resulting in the SRG structure. This process is explained by the Marangoni flow triggered by the photoinduced surface tension change of the surface layer. In this work, we newly propose that the same strategy is applicable to an amorphous polymer material of polystyrene. The results obtained here indicate that photoinduced SRG formation is expanded for general amorphous polymers.
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