镧系元素
锕系元素
化学
组合化学
溶解度
镅
纳米技术
无机化学
物理化学
有机化学
材料科学
离子
作者
Henk H. Dam,David N. Reinhoudt,Willem Verboom
摘要
In nuclear waste treatment processes there is a need for improved ligands for the separation of actinides (An(III)) and lanthanides (Ln(III)). Several research groups are involved in the design and synthesis of new An(III) ligands and in the confinement of these and existing An(III) ligands onto molecular platforms giving multicoordinate ligands. The preorganization of ligands considerably improves the An(III) extraction properties, which are largely dependent on the solubility and rigidity of the platform. This tutorial review summarizes the most important An(III) ligands with emphasis on the preorganization strategy using (macrocyclic) platforms.
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