材料科学
光子上转换
发光
兴奋剂
纳米颗粒
分析化学(期刊)
镱
透射电子显微镜
纳米材料
纳米技术
光电子学
化学
色谱法
作者
Ye Kuang,Tianyao Li,Tao Jia,Arif Gulzar,Chongna Zhong,Shili Gai,Fei He,Piaoping Yang,Jun Lin
出处
期刊:Small
[Wiley]
日期:2020-10-01
卷期号:16 (43)
被引量:24
标识
DOI:10.1002/smll.202003799
摘要
Abstract It is absolutely imperative for development of material science to adjust upconversion luminescence (UCL) properties of highly doped upconversion nanoparticles (UCNPs) with special optical properties and prominent application prospects. In this work, featuring NaHoF 4 @NaYbF 4 (Ho@Yb) structures, sub‐30 nm core–multishell UCNPs are synthesized with a small NaHoF 4 core and varied Gd 3+ /Yb 3+ coexisting shells. X‐ray diffraction, transmission electron microscopy, UCL spectrum, UCL lifetime, and pump power dependence are adhibited for characterization. Compared with the former work, except for a smaller total size, tunable emission in color from red to yellow to green, and intensity from low to stronger than that of traditional UCNPs is achieved for ≈ 10 nm NaHoF 4 core size by means of changing number of layers and Gd 3+ /Yb 3+ concentration ratios in different layers. Besides, simultaneously doping Ho 3+ into the shells will result in lowered UCL intensity and lifted green/red ratio. Surface energy loss and sensitizing energy supply, which can be modulated with inert shielding of Gd 3+ and sensitization of Yb 3+ , are proved to be the essential determinant. More UCL properties of these peculiar Ho@Yb UCNPs are uncovered and detailedly summarized, and the findings can help to expand the application scope of NaHoF 4 into photoinduced therapy.
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