加氢脱氧
化学
钼
催化作用
氢
光化学
氢溢流
等离子体子
青铜色
烷基
无机化学
有机化学
冶金
选择性
光电子学
材料科学
作者
Yasutaka Kuwahara,Masahiro Okada,Hao Ge,Hiromi Yamashita
出处
期刊:Chemistry Letters
[The Chemical Society of Japan]
日期:2021-12-28
卷期号:51 (2): 166-169
被引量:3
摘要
Abstract Reduction of α-MoO3via “hydrogen spillover” process mediated by noble metal nanoparticles leads to a formation of hydrogen molybdenum bronze with plasmon-induced optical features. We herein report that Pd-loaded hydrogen molybdenum bronze effectively promotes the hydrodeoxygenation of aromatic ketones to the corresponding alkyl aromatics at room temperature and under atmospheric pressure of H2. The catalyst shows a further enhanced catalytic activity under the irradiation of visible light due to the plasmonic effect.
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