阳极
材料科学
成核
枝晶(数学)
箔法
基质(水族馆)
涂层
化学工程
电解质
沉积(地质)
电偶阳极
冶金
纳米技术
复合材料
电极
化学
阴极保护
古生物学
几何学
数学
海洋学
有机化学
物理化学
沉积物
工程类
生物
地质学
作者
Bo Hu,Kang Han,Chunhua Han,Lishan Geng,Ming Li,Ping Hu,Xuanpeng Wang
出处
期刊:Coatings
[MDPI AG]
日期:2022-05-12
卷期号:12 (5): 661-661
被引量:2
标识
DOI:10.3390/coatings12050661
摘要
Aluminum-ion batteries have attracted great interest in the grid-scale energy storage field due to their good safety, low cost and the high abundance of Al. However, Al anodes suffer from severe dendrite growth, especially at high deposition rates. Here, we report a simple strategy for constructing a highly reversible, dendrite-free, Al-based anode through directly introducing a solid-solution-based metal coating to a Zn foil substrate. Compared with Cu foil substrates and bare Al, a Zn foil substrate shows a lower nucleation barrier of Al deposition due to the intrinsic, definite solubility between Al and Zn. During Al deposition, a thin, solid-solution alloy phase is first formed on the surface of the Zn foil substrate and then guides the parallel growth of flake-like Al on Zn substrate. The well-designed, Zn-coated Al (Zn@Al) anode can effectively inhibit dendrite growth and alleviate the corrosion of the Al anode. The fabricated Zn@Al–graphite battery exhibits a high specific capacity of 80 mAh·g−1 and an ultra-long lifespan over 10,000 cycles at a high current density of 20 A·g−1 in low-cost molten salt electrolyte. This work opens a new avenue for the development of stable Al anodes and can provide insights for other metal anode protection.
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