化学
锡烷
全合成
动力学分辨率
单体
立体化学
催化作用
组合化学
有机化学
对映选择合成
聚合物
作者
Tian Qin,John A. Porco
标识
DOI:10.1002/anie.201311260
摘要
Abstract Total syntheses of the dimeric tetrahydroxanthone natural products secalonic acids A and D are described. Key steps involve kinetic resolution of the tetrahydroxanthone core structure using homobenzotetramisole catalysis and late‐stage copper(I)‐mediated homodimerization of complex aryl stannane monomers.
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