A Hybrid Solid with Giant Pores Prepared by a Combination of Targeted Chemistry, Simulation, and Powder Diffraction

Angewandte Chemie International EditionVolume 43, Issue 46 p. 6296-6301 Communication A Hybrid Solid with Giant Pores Prepared by a Combination of Targeted Chemistry, Simulation, and Powder Diffraction Gérard Férey, Gérard Férey [email protected] Institut universitaire de France, Fax:(+33) 1-3925-4358 Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, FranceSearch for more papers by this authorChristian Serre, Christian Serre Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, FranceSearch for more papers by this authorCaroline Mellot-Draznieks, Caroline Mellot-Draznieks Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, FranceSearch for more papers by this authorFranck Millange, Franck Millange Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, FranceSearch for more papers by this authorSuzy Surblé, Suzy Surblé Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, FranceSearch for more papers by this authorJulien Dutour, Julien Dutour Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, FranceSearch for more papers by this authorIrène Margiolaki, Irène Margiolaki ESRF, Grenoble, FranceSearch for more papers by this author Gérard Férey, Gérard Férey [email protected] Institut universitaire de France, Fax:(+33) 1-3925-4358 Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, FranceSearch for more papers by this authorChristian Serre, Christian Serre Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, FranceSearch for more papers by this authorCaroline Mellot-Draznieks, Caroline Mellot-Draznieks Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, FranceSearch for more papers by this authorFranck Millange, Franck Millange Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, FranceSearch for more papers by this authorSuzy Surblé, Suzy Surblé Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, FranceSearch for more papers by this authorJulien Dutour, Julien Dutour Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, FranceSearch for more papers by this authorIrène Margiolaki, Irène Margiolaki ESRF, Grenoble, FranceSearch for more papers by this author First published: 23 November 2004 https://doi.org/10.1002/anie.200460592Citations: 778Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract A perfect combination: The association of a chromium(III) trimeric building unit and 1,3,5-benzenetricarboxylate led to the powdered solid MIL-100. Simulations provided a crystal structure solution, which matched the experimental powder XRD pattern. This unique simulation/diffraction combination allowed the structure determination of a giant-pore solid with a zeotype architecture, built up from hybrid supertetrahedra (see picture). Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2004/z460592_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1G. Férey, A. K. Cheetham, Science 1999, 283, 1125–1126; G. Férey, Science 2000, 289, 994–995. 2H. Li, M. Eddaoudi, M. O'Keeffe, O. M. Yaghi, Nature 1999, 402, 276–279. 3O. M. Yaghi, M. O'Keeffe, N. W. Ockwig, H. K. Chae, M. Eddaoudi, J. Kim, Nature 2003, 423, 705–714; M. Eddaoudi, J. Kim, N. Rosi, D. Vodak, J. Wachter, M. O'Keeffe, O. M. Yaghi, Science 2002, 295, 469–472. 4L. Beitone, C. Huguenard, M. Henry, F. Taulelle, T. Loiseau, G. Férey, J. Am. Chem. Soc. 2003, 125, 9102–9110. 5A. Müller, E. Krickemeyer, H. Bögge, M. Schmidtmann, S. Roy, A. Berkle, Angew. Chem. 2002, 114, 3756–3761; Angew. Chem. Int. Ed. 2002, 41, 3604–3609; A. Müller, S. K. Das, S. Talismanov, S. Roy, E. Beckmann, H. Bögge, M. Schmidtmann, A. Merca, A. Berkle, L. Allouche, Y. Zhou, L. Zhang, Angew. Chem. 2003, 115, 5193–5198; Angew. Chem. Int. Ed. 2003, 42, 5039–5044. 6N. Guillou, P. M. Forster, Q. Gao, J. S. Chang, M. Nogues, S.-E. Park, A. K. Cheetham, G. Férey, Angew. Chem. 2001, 113, 2913–2916; Angew. Chem. Int. Ed. 2001, 40, 2831–2834. 7F. Schüth, K. S. W. Sing in Handbook of Porous Solids (Eds.: ), Wiley-VCH, Weinheim, 2002. 8S. Kitagawa, M. Kondo, Bull. Chem. Soc. Jpn. 1998, 71, 1739–1753; P. M. Forster, J. Eckert, J.-S. Chang, S.-E. Park, G. Férey, A. K. Cheetham, J. Am. Chem. Soc. 2003, 125, 1309–1312; N. Rosi, J. Eckert, M. Eddaoudi, D. Vodak, J. Kim, M. O'Keeffe, O. M. Yaghi, Science 2003, 300, 1127–1129; G. Férey, M. Latroche, C. Serre, F. Millange, T. Loiseau, A. Percheron-Guégan, Chem. Commun. 2003, 2276. 9G. Férey, J. Solid State Chem. 2000, 152, 37–48; G. Férey, J. Solid State Sci. 2003, 5, 79–94. 10O. M. Yaghi, M. O'Keeffe, M. Kanatzidis, J. Solid State Chem. 2000, 152, 1–321. 11M. Eddaoudi, D. B. Moler, H. Li, B. Chen, T. M. Reineke, M. O'Keeffe, O. M. Yaghi, Acc. Chem. Res. 2001, 34, 319–330. 12O. Delgado-Friedrichs, M. O'Keeffe, O. M. Yaghi, Acta Crystallogr. Sect. A 2003, 59, 22–27. 13C. Mellot-Draznieks, J. Dutour, G. Férey, Angew. Chem. 2004, 116, 6450–6456; Angew. Chem. Int. Ed. 2004, 43, 6290–6296. 14C. Mellot-Draznieks, J. M. Newsam, A. M. Gorman, C. M. Freeman, G. Férey, Angew. Chem. 2000, 112, 2258–2363; Angew. Chem. Int. Ed. 2000, 39, 2270–2275; C. Mellot-Draznieks, S. Girard, G. Férey, C. Schön, Z. Cancarevic, M. Jansen, Chem. Eur. J. 2002, 8, 4103–4113; C. Mellot-Draznieks, S. Girard, G. Férey, J. Am. Chem. Soc. 2002, 124, 15 326–15 335. 15C. Serre, F. Millange, S. Surblé, G. Férey, Angew. Chem. 2004, 116, 6445–6449; Angew. Chem. Int. Ed. 2004, 43, 6285–6289. 16J. S. Seo, D. Wang, H. Lee, S. I. Jun, J. Oh, Y. J. Jeon, K. Kim, Nature 2000, 404, 982–986. 17R. De Pape, G. Férey, Mater. Res. Bull. 1986, 21, 971–978. 18M. O'Keeffe, S. Andersson, Acta Crystallogr. Sect. A 1977, 33, 914–923; S. Lidin, M. Jacob, S. Andersson, J. Solid State Chem. 1995, 114, 36–41. 19M. M. J. Treacy, J. B. Higgins in Collection of Simulated XRD Powder Patterns for Zeolites, 4th ed., Elsevier 2001, and http://www.iza-structure.org/databases/. 20H. K. Chae, D. Y. Siberio-Perez, J. Kim, Y.-B. Go, M. Eddaoudi, A. J. Matzger, M. O'Keeffe, O. M. Yaghi, Nature 2004, 427, 523–527. Citing Literature Volume43, Issue46November 26, 2004Pages 6296-6301 This article also appears in:Gérard Férey ReferencesRelatedInformation