Characteristic guaiane sesquiterpenes from Daphne penicillata and ECD/NMR-based assignment of C-1 configuration

40 compounds including the first C17 homo-guaiane sesquiterpene (1) were isolated from Daphne penicillata and an efficient method using ECD/NMR strategy to access the C-1 configuration of characteristic guaiane sesquiterpenes has been developed.