热电性
极化
材料科学
侧链
极化(电化学)
结晶
微晶
烷基
结晶学
电压
化学物理
铁电性
光电子学
化学工程
电介质
有机化学
复合材料
聚合物
物理化学
化学
冶金
物理
量子力学
工程类
作者
Azumi Akiyama,Hyuma Masu,Michinari Kohri,Keiki Kishikawa
标识
DOI:10.1016/j.matlet.2023.134363
摘要
Tetraalkoxylated diphenylureas U-3,4-Scit and U-3,4-raccit were synthesized from chiral and racemic citronellyl bromides as starting materials, respectively. To prepare pyroelectric crystals, these two compounds were slowly cooled from their molten states. Although the two compounds have very similar molecular structures, they exhibited quite different electric-field responsiveness. U-3,4-Scit spontaneously polarized during the crystallization process, and almost no polarization switching was observed. On the other hand, U-3,4-raccit exhibited polarization switching in its crystalline state at a high-temperature range, and the polarization direction could be fixed by cooling the crystal to room temperature while applying a direct current voltage. This flexibility occurs because the alkyl chain parts in the crystal are disordered. These pyroelectric thin films are promising materials, as they function in a polycrystalline state without poling treatment.
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