Effect of microstructure and grain boundary character distribution on the corrosion behavior of weathering bridge steel

Purpose This study aims to investigate the effect of different microstructures and its grain boundary character distribution (GBCD) on the corrosion behavior of weathering bridge steel. Design/methodology/approach The rust layer characteristics and corrosion resistance of specimens with different microstructures in the simulated industrial environment were studied by Electron Probe X-ray Micro-Analyzer, wavelength-dispersive spectrometer and electrochemical techniques. Electron backscatter diffraction technique was used to characterize the GBCD in steels with different microstructures. Findings Results revealed a significant difference in the corrosion susceptibility among the four microstructures, with corrosion rates decreasing in the following order: ferrite + pearlite > ferrite + bainite > bainite > martensite. The variation in corrosion resistance is primarily influenced by the microstructure type and the proportion of special grain boundaries, rather than the alloying elements. The proportion of Σ3 boundaries within the coincidence site lattice boundaries is positively correlated with improved corrosion resistance. A higher Σ3 boundary fraction resulted in a lower effective grain boundary energy, elevated self-corrosion potential, increased polarization resistance and reduced areas of localized galvanic corrosion; this led to enhanced inhibition of the electrochemical corrosion reaction, consequently reducing the corrosion rate. Originality/value This study elucidates and quantifies the intrinsic relationship between microstructure, GBCD and corrosion rate. This understanding is crucial for enhancing the corrosion resistance of weathering bridge steels in industrial atmospheric corrosion environments.