High temperature melting of municipal solid waste incineration (MSWI) fly ash and co-disposal technology with blast furnaces

焚化 废物管理 粉煤灰 城市固体废物 熔渣(焊接) 碱度 燃烧 环境科学 磨细高炉矿渣 煤燃烧产物 高炉 冶金 化学 工程类 材料科学 有机化学
作者
Xiaodong Ping,Feng Wang,Haifeng Wang,Jianlei Pan,Lijin Lu,Jian Qiu
出处
期刊:Waste Management [Elsevier BV]
卷期号:183: 191-198 被引量:11
标识
DOI:10.1016/j.wasman.2024.05.016
摘要

With the development of municipal solid waste incineration technologies, the disposal of fly ash has become a difficult problem that many countries need to solve. High-temperature melting is a promising disposal technology. Based on this, a new process for collaborative treatment of fly ash in metallurgical blast furnaces had been proposed in this study. To explore the impact of disposal of fly ash on blast furnace production, by simulating the high-temperature reducing environment of blast furnaces, the melting changes of water-washed fly ash (W-FA), and the effects of W-FA injection on coal combustion and products (slag, iron) composition were studied. The results showed that W-FA, as a flux, could be sprayed into the blast furnace separately or mixed with coal. But when injected along with coal, W-FA would suppress the combustion of coal. After melting, the removal rates of S, P, Cl, and Pb in W-FA were 21%, 30%, 86%, and 89%, respectively. The removal rates of K, Na, and Zn were close to 100%, and Cr was basically not removed. When the proportion of W-FA to coal was less than 1%, in addition to controlling the alkalinity of the slag, the impact of W-FA on the composition of iron and slag was minimal. The successful execution of this work will not only achieve the reduction, harmless and resourceful utilization of fly ash, but also save investment and operating costs of disposal facilities, with both environmental and social benefits.
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