X射线吸收精细结构
催化作用
电解质
吸附
电化学
氢
化学
氧气
无机化学
碳纤维
化学工程
材料科学
电极
物理化学
有机化学
物理
工程类
复合材料
复合数
量子力学
光谱学
作者
Naoki Yamamoto,Daiju Matsumura,Yuto Hagihara,Kei Tanaka,Yuta Hasegawa,Kenji Ishii,Hiroyuki Tanaka
标识
DOI:10.1016/j.jpowsour.2022.232508
摘要
Oxygen Reduction Reaction (ORR) is one of the key electrochemical reactions, especially in Polymer Electrolyte Fuel Cells (PEFCs). In this work, the reaction pathway and intermediate species such as molecular-type oxygen during ORR were discussed. High energy resolution X-ray absorption fine structure spectra at the Pt L3-edge were obtained to observe the electronic structure of Pt catalyst. Carbon-supported Pt nanoparticles as powder catalysts were used for measurement as more realistic conditions, and the species adsorbed on the Pt nanoparticles were analyzed while controlling under the potentials in acidic electrolyte solution with N2 or O2 gas bubbling. Molecular-type oxygen adsorption species is observed only in the O2-bubbled electrolyte solution. This intermediate adsorption species is assigned to a hydrogen superoxide.
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