材料科学
电解质
阳极
法拉第效率
石墨烯
化学工程
阴极
金属锂
电极
纳米技术
金属
冶金
工程类
物理化学
化学
作者
Pengbo Zhai,Tianshuai Wang,Huaning Jiang,Jiayu Wan,Yi Wei,Lei Wang,Wei Liu,Chen Qian,Weiwei Yang,Yi Cui,Yongji Gong
标识
DOI:10.1002/adma.202006247
摘要
Abstract Despite considerable efforts to prevent lithium (Li) dendrite growth, stable cycling of Li metal anodes with various structures remains extremely difficult due to the direct contact of the liquid electrolyte with Li. Rational design of solid‐electrolyte interphase (SEI) for 3D electrodes is a promising but still challenging strategy for preventing Li dendrite growth and avoiding lithium–electrolyte side reactions in Li‐metal batteries. Here, a 3D architecture is constructed with g‐C 3 N 4 /graphene/g‐C 3 N 4 insulator–metal–insulator sandwiched nanosheets to guide uniform Li plating/stripping in the van der Waals gap between the graphene and the g‐C 3 N 4 , and the function of which can be regarded as a 3D artificial SEI. Li deposition on the surface of g‐C 3 N 4 is suppressed due to its insulating nature. However, its uniform lithiophilic sites and nanopore channels enable homogeneous lithium plating between the graphene and the g‐C 3 N 4 , prohibiting the direct contact of the electrolyte with the Li metal. The use of the g‐C 3 N 4 ‐layer‐modified 3D anode enables long‐term Li deposition with a high Coulombic efficiency and stable cycling of full cells under high cathode loading, limited Li excess, and lean electrolyte conditions. The concept of a 3D artificial SEI will shed light on developing safe and stable Li‐metal anodes.
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