化学
胺化
亲电胺化
试剂
还原胺化
组合化学
氧化还原
电泳剂
小学(天文学)
有机化学
光化学
催化作用
物理
天文
作者
Vishala Maharaj,Preeti P. Chandrachud,Wen Che,Łukasz Wojtas,Justin M. Lopchuk
出处
期刊:Organic Letters
[American Chemical Society]
日期:2021-11-08
卷期号:23 (22): 8838-8842
被引量:23
标识
DOI:10.1021/acs.orglett.1c03344
摘要
Diazirines have been recently demonstrated to serve as electrophilic amination reagents that afford diaziridines, versatile heterocycles that are readily transformed into amines, hydrazines, and nitrogen-containing heterocycles. Here, we report the photodecarboxylative amination of redox-active esters with diazirines using inexpensive photoactivators under mild conditions with an enhanced scope for primary substrates. The stability of diazirines to blue light is demonstrated, paving the way for further research into other photochemical amination methods with these unique heterocycles.
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