对苯二酚
半醌
化学
醌
质子化
电化学
质子
质子耦合电子转移
电子转移
光化学
氧化还原
二聚体
无机化学
物理化学
电极
有机化学
离子
物理
量子力学
作者
Brian R. Eggins,James Q. Chambers
出处
期刊:Journal of The Electrochemical Society
[The Electrochemical Society]
日期:1970-01-01
卷期号:117 (2): 186-186
被引量:169
摘要
Electrochemical and spectroscopic techniques have been used to study the benzo‐, duro‐, tetrachloro‐, and p‐xyloquinone‐hydroquinone couples in nonaqueous solvents. The proton transfer reactions which are coupled to the electron transfer steps are elucidated. Oxidation of the hydroquinone leads to the protonated quinone species, while reduction of the quinones in the presence of a proton source gives mixtures of the corresponding hydroquinone, its conjugate base, and the free semiquinone, depending on the amount and strength of the proton donor used. Oxidation of the hydroquinones is postulated to proceed via a dimer of the one‐electron intermediate. Preliminary results are reported on the electrochemical behavior of solutions containing the quinhydrone charge‐transfer complex.
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