质子交换膜燃料电池
电极
阴极
材料科学
毛细管作用
气体扩散
氧气输送
多孔性
体积流量
膜电极组件
两相流
水运
分析化学(期刊)
复合材料
化学
机械
流量(数学)
化学工程
阳极
燃料电池
水流
色谱法
氧气
环境工程
有机化学
物理化学
工程类
物理
作者
Wensheng He,Jung S. Yi,Trung Van Nguyen
出处
期刊:Aiche Journal
[Wiley]
日期:2000-10-01
卷期号:46 (10): 2053-2064
被引量:486
标识
DOI:10.1002/aic.690461016
摘要
Abstract When interdigitated gas distributors are used in a PEM fuel cell, fluids entering the fuel cell are forced to flow through the electrodes porous layers. This characteristic increases transport rates of the reactants and products to and from the catalyst layers and reduces the amount of liquid water entrapped in the porous electrodes thereby minimizing electrode flooding. To investigate the effects of the gas and liquid water hydrodynamics on the performance of an air cathode of a PEM fuel cell employing an interdigitated gas distributor, a 2‐D, two‐phase, multicomponent transport model was developed. Darcy's law was used to describe the transport of the gas phase. The transport of liquid water through the porous electrode is driven by the shear force of gas flow and capillary force. An equation accounting for both forces was derived for the liquid phase transport in the porous gas electrode. Higher differential pressures between inlet and outlet channels yield higher electrode performance, because the oxygen transport rates are higher and liquid water removal is more effective. The electrode thickness needs to be optimized to get optimal performance because thinner electrode may reduce gas‐flow rate and thicker electrode may increase the diffusion layer thickness. For a fixed‐size electrode, more channels and shorter shoulder widths are preferred.
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