亲爱的研友该休息了!由于当前在线用户较少,发布求助请尽量完整的填写文献信息,科研通机器人24小时在线,伴您度过漫漫科研夜!身体可是革命的本钱,早点休息,好梦!

Direct conversion of degraded LiCoO2 cathode materials into high-performance LiCoO2: A closed-loop green recycling strategy for spent lithium-ion batteries

材料科学 锂钴氧化物 阴极 电池(电) 锂(药物) 浸出(土壤学) 锂离子电池 冶金 化学 环境科学 医学 物理 内分泌学 物理化学 土壤科学 土壤水分 功率(物理) 量子力学
作者
Junxiong Wang,Zheng Liang,Yun Zhao,Jinzhi Sheng,Jun Ma,Kai Jia,Baohua Li,Guangmin Zhou,Hui‐Ming Cheng
出处
期刊:Energy Storage Materials [Elsevier]
卷期号:45: 768-776 被引量:135
标识
DOI:10.1016/j.ensm.2021.12.013
摘要

Lithium cobalt oxide (LiCoO2) is the most widely used cathode materials for smart phones and laptop batteries. With the rapid development of portable electronics, more than 100,000 tons of spent lithium-ion batteries (LIBs) are produced every year. Conventional battery recycling processes including pyrometallurgical and hydrometallurgical processes mainly aim at extracting valuable metallic components from spent LIB cathodes, which requires high temperature reduction and/or acid/alkali chemicals to destroy covalent bond in cathodes and convert them into atoms for further extraction. The former leads to high energy consumption and the latter produces a lot of wastewater, which not only increases cost, but also damages our environment. Moreover, traditional recycling starts from spent battery cathodes and ends up with lithium/cobalt salts, which is unsustainable. Herein, a different recycling strategy to directly convert degraded LiCoO2 into high-voltage LiCoO2 cathode materials was proposed, featuring a closed-loop and green procedure. The directly-converted LiCoO2 from spent cathodes exhibits excellent cyclability at 4.5 V with a high capacity retention of 97.4% after 100 cycles, even superior than pristine LiCoO2. The recovery efficiencies of lithium and cobalt reach 91.3% and 93.5%, respectively, and the energy consumption could be greatly reduced since the roasting temperature was dropped below 400 °C with the assistance of ammonium sulfate. Due to the utilization of low-cost reagents and water as the leaching agent, the potential benefit of the recovery process was estimated to reach 6.94 $/kg cell.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
大幅提高文件上传限制,最高150M (2024-4-1)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
20秒前
23秒前
lsx发布了新的文献求助10
40秒前
lsx完成签到,获得积分10
51秒前
1分钟前
南寅完成签到,获得积分10
1分钟前
谨慎颜演完成签到 ,获得积分10
1分钟前
1分钟前
研友_VZG7GZ应助科研通管家采纳,获得10
1分钟前
Jasper应助科研通管家采纳,获得10
1分钟前
Amber完成签到 ,获得积分10
1分钟前
wodetaiyangLLL完成签到 ,获得积分10
1分钟前
1分钟前
1分钟前
研友_VZG7GZ应助aaaaa采纳,获得10
2分钟前
2分钟前
aaaaa发布了新的文献求助20
2分钟前
vvan发布了新的文献求助10
3分钟前
樱桃猴子应助科研通管家采纳,获得10
3分钟前
樱桃猴子应助科研通管家采纳,获得10
3分钟前
3分钟前
micomico完成签到 ,获得积分10
3分钟前
魔幻的代珊应助LYL采纳,获得10
3分钟前
aaaaa完成签到,获得积分10
4分钟前
下次一定发布了新的文献求助10
4分钟前
4分钟前
丁宇卓完成签到 ,获得积分10
4分钟前
4分钟前
胡涛涛发布了新的文献求助10
4分钟前
传奇3应助harrywoo采纳,获得10
5分钟前
胡涛涛完成签到,获得积分20
5分钟前
5分钟前
我是老大应助胡涛涛采纳,获得10
5分钟前
曹原阁完成签到 ,获得积分10
5分钟前
5分钟前
5分钟前
天天好心覃完成签到 ,获得积分10
6分钟前
6分钟前
zqq完成签到,获得积分0
6分钟前
咸鱼卷完成签到 ,获得积分10
6分钟前
高分求助中
The ACS Guide to Scholarly Communication 2500
Sustainability in Tides Chemistry 2000
Pharmacogenomics: Applications to Patient Care, Third Edition 1000
Studien zur Ideengeschichte der Gesetzgebung 1000
TM 5-855-1(Fundamentals of protective design for conventional weapons) 1000
Threaded Harmony: A Sustainable Approach to Fashion 810
Genera Insectorum: Mantodea, Fam. Mantidæ, Subfam. Hymenopodinæ (Classic Reprint) 800
热门求助领域 (近24小时)
化学 医学 生物 材料科学 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 基因 遗传学 催化作用 物理化学 免疫学 量子力学 细胞生物学
热门帖子
关注 科研通微信公众号,转发送积分 3085426
求助须知:如何正确求助?哪些是违规求助? 2738274
关于积分的说明 7548805
捐赠科研通 2387902
什么是DOI,文献DOI怎么找? 1266200
科研通“疑难数据库(出版商)”最低求助积分说明 613332
版权声明 598569