Direct conversion of degraded LiCoO2 cathode materials into high-performance LiCoO2: A closed-loop green recycling strategy for spent lithium-ion batteries

材料科学 锂钴氧化物 阴极 电池(电) 锂(药物) 浸出(土壤学) 锂离子电池 冶金 化学 环境科学 医学 物理 内分泌学 物理化学 土壤科学 土壤水分 功率(物理) 量子力学
作者
Junxiong Wang,Zheng Liang,Yun Zhao,Jinzhi Sheng,Jun Ma,Kai Jia,Baohua Li,Guangmin Zhou,Hui‐Ming Cheng
出处
期刊:Energy Storage Materials [Elsevier]
卷期号:45: 768-776 被引量:139
标识
DOI:10.1016/j.ensm.2021.12.013
摘要

Lithium cobalt oxide (LiCoO2) is the most widely used cathode materials for smart phones and laptop batteries. With the rapid development of portable electronics, more than 100,000 tons of spent lithium-ion batteries (LIBs) are produced every year. Conventional battery recycling processes including pyrometallurgical and hydrometallurgical processes mainly aim at extracting valuable metallic components from spent LIB cathodes, which requires high temperature reduction and/or acid/alkali chemicals to destroy covalent bond in cathodes and convert them into atoms for further extraction. The former leads to high energy consumption and the latter produces a lot of wastewater, which not only increases cost, but also damages our environment. Moreover, traditional recycling starts from spent battery cathodes and ends up with lithium/cobalt salts, which is unsustainable. Herein, a different recycling strategy to directly convert degraded LiCoO2 into high-voltage LiCoO2 cathode materials was proposed, featuring a closed-loop and green procedure. The directly-converted LiCoO2 from spent cathodes exhibits excellent cyclability at 4.5 V with a high capacity retention of 97.4% after 100 cycles, even superior than pristine LiCoO2. The recovery efficiencies of lithium and cobalt reach 91.3% and 93.5%, respectively, and the energy consumption could be greatly reduced since the roasting temperature was dropped below 400 °C with the assistance of ammonium sulfate. Due to the utilization of low-cost reagents and water as the leaching agent, the potential benefit of the recovery process was estimated to reach 6.94 $/kg cell.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
大幅提高文件上传限制,最高150M (2024-4-1)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
小北完成签到,获得积分10
刚刚
假面绅士发布了新的文献求助10
2秒前
舒适的易烟完成签到,获得积分10
3秒前
老火发布了新的文献求助10
3秒前
端庄的绯发布了新的文献求助10
4秒前
LI完成签到,获得积分10
4秒前
CodeCraft应助高贵季节采纳,获得10
4秒前
顾矜应助CY采纳,获得10
5秒前
neinei完成签到 ,获得积分10
5秒前
6秒前
科研通AI2S应助假面绅士采纳,获得10
7秒前
科研通AI2S应助假面绅士采纳,获得10
7秒前
大方的板栗完成签到,获得积分10
8秒前
淡然的手套完成签到,获得积分10
8秒前
cuber完成签到 ,获得积分10
8秒前
Jasper应助天啊采纳,获得10
8秒前
9秒前
9秒前
自行者发布了新的文献求助10
10秒前
12秒前
完美世界应助老火采纳,获得10
12秒前
彩虹完成签到,获得积分10
13秒前
xqy发布了新的文献求助10
13秒前
小立发布了新的文献求助10
14秒前
15秒前
烟花应助迅速弘文采纳,获得10
15秒前
16秒前
16秒前
lily88发布了新的文献求助10
17秒前
17秒前
guilin给libaibai的求助进行了留言
19秒前
PN_Allen完成签到 ,获得积分10
19秒前
中中发布了新的文献求助10
19秒前
19秒前
20秒前
阿连发布了新的文献求助10
21秒前
阿耒完成签到,获得积分20
21秒前
CY发布了新的文献求助10
21秒前
NexusExplorer应助SADHIASK采纳,获得10
21秒前
蓬蒿人完成签到 ,获得积分10
22秒前
高分求助中
The Young builders of New china : the visit of the delegation of the WFDY to the Chinese People's Republic 1000
юрские динозавры восточного забайкалья 800
English Wealden Fossils 700
Chen Hansheng: China’s Last Romantic Revolutionary 500
宽禁带半导体紫外光电探测器 388
COSMETIC DERMATOLOGY & SKINCARE PRACTICE 388
Case Research: The Case Writing Process 300
热门求助领域 (近24小时)
化学 医学 生物 材料科学 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 基因 遗传学 催化作用 物理化学 免疫学 量子力学 细胞生物学
热门帖子
关注 科研通微信公众号,转发送积分 3142138
求助须知:如何正确求助?哪些是违规求助? 2793085
关于积分的说明 7805514
捐赠科研通 2449427
什么是DOI,文献DOI怎么找? 1303274
科研通“疑难数据库(出版商)”最低求助积分说明 626807
版权声明 601291