Preparation of Stable POSS-Based Superhydrophobic Textiles Using Thiol–Ene Click Chemistry

In this study, a superhydrophobic fabric was synthesized by modifying the fiber's surface with dopamine-containing hydroxyl functional groups. Furthermore, we introduced mercapto-based functional groups by the hydrolysis of mercaptopropylmethyldimethoxysilane (MPMDS) and finally grafted POSS and mercaptans using a thiol-ene click reaction. These processes generated a superhydrophobic fabric with a static contact and a sliding angle of 162° and 8°, respectively. The superhydrophobic fabric's compact and regular micro-nano rough structure based on POSS and mercaptans provides stable fastness and durability, as well as high resistance to organic solvents, acid-base environments, mechanical abrasion, UV rays, and washing. Moreover, it can be used for self-cleaning and oil-water separation, and it has a wide range of applications in the coating industry.