Orientation Manipulation and Defect Passivation for Perovskite Solar Cells by a Natural Compound

Abstract Different facets in perovskite crystals exhibit distinct atomic arrangements, influencing their electronic, physical, and chemical properties. Perovskite films incorporating tin oxide (SnO 2 ) as the electron transport layer face challenges in facet regulation. This study reveals that tea saponin (TS), a natural compound serves as a SnO 2 modifier, facilitates optimal growth of perovskite crystals on the (111) facet. The modification promotes preferential crystal orientation through hydrogen bond and Lewis coordination. TS forms a chelate with SnO 2 , resulting in a smoother film and n‐type doping, leading to improved carrier extraction and reduced defects. The TS‐modified perovskite solar cells achieve a champion efficiency of 24.2%, leveraging from an obvious enhancement of open‐circuit voltage ( V oc ) of 1.18 V and fill factor (FF) of 82.8%. The devices also demonstrate enhanced humidity tolerance and storage stability, ensuring improved stability without encapsulation.