插层(化学)
离子
电化学
磺酸盐
动力学
扩散
材料科学
电极
化学
电子转移
无机化学
化学工程
光化学
物理化学
有机化学
冶金
物理
量子力学
工程类
热力学
钠
作者
Xin Liu,M. Le Dû,Shunri Zheng,Kar Ban Tan,Cuimei Zhao,Junyan Li,Qinhua Gu,Wenjuan Han,Shichong Xu,Ming Lu,Haibo Li,Bingsen Zhang
出处
期刊:Carbon
[Elsevier]
日期:2024-01-14
卷期号:219: 118828-118828
被引量:3
标识
DOI:10.1016/j.carbon.2024.118828
摘要
Ion pre-intercalation regulating the tunnel structure of electrode materials accelerates Zn2+ insertion kinetics to realize a high energy storage contribution of Zn-ion batteries. However, electrostatic interaction induced by the pre-intercalated cation and multivalent Zn2+ ions hinders the insertion of Zn2+/H+. In order to retain the negative interlayer surface, herein, OTf− anions were intercalated into the confined spacing by MXene via an electrochemical-driven method. Without changing the potential state of the interlayer spacings, OTf− anion induced a regulated interlayer distance, and a higher oxidation state of V based on the space occupation and the electron transfer mechanism. Consequently, the zinc ion storage capacity of V2CTx MXene increases from 125.2 to 288.7 mAh/g at 0.5 A/g. Interestingly, the negatively charged MXene surface was still intact, which presents lower diffusion barriers of the Zn2+ ions. The merits of anion pre-intercalation are highlighted and provide new insights into the ion storage function-oriented design of MXene.
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