Controlled Synthesis of Polymers†

Comprehensive Summary Controlled synthesis is central to obtaining polymers with accurate structures and excellent performances. Recent research in the controlled synthesis of polymers has focused on optimizing monomers, initiation systems, and reaction conditions. The satisfactory sequence, topological structure, and dispersity have been achieved to satisfy the growing demand for functional polymers. This review summarizes the selection of monomers of various types and structures, the innovation of initiation systems, and the optimization of reaction conditions in the controlled synthesis of polymers and discusses their challenges and opportunities.