Liquid phase catalytic transfer hydrogenation of furfural over a Ru/C catalyst

糠醛 糠醇 呋喃 催化作用 化学 氢解 有机化学 产量(工程) 选择性 材料科学 冶金
作者
Paraskevi Panagiotopoulou,Dionisios G. Vlachos
出处
期刊:Applied Catalysis A-general [Elsevier]
卷期号:480: 17-24 被引量:210
标识
DOI:10.1016/j.apcata.2014.04.018
摘要

Methyl furan production through catalytic transfer hydrogenation of furfural in the liquid phase has been investigated over a Ru/C catalyst in the temperature range of 120–200 °C using 2-propanol as a solvent. It has been found that furfural hydrogenation produces furfuryl alcohol, which undergoes hydrogenolysis to methyl furan. Small amounts of furan and traces of tetrahydrofurfuryl alcohol are also produced via furfural decarbonylation and furfuryl alcohol ring hydrogenation, respectively. Furfuryl alcohol can dimerize or produce ether with 2-propanol. The yield of methyl furan is enhanced with increasing reaction temperature and/or reaction time. Optimum results are attained after 10 h of reaction at 180 °C, where furfural conversion and methyl furan yield reach 95% and 61%, respectively, which is the highest reported yield in the liquid phase at temperatures lower than 200 °C. The reaction network has been investigated by analysing the evolution of reaction intermediates and products and by starting from furfuryl alcohol, methyl furan, and furan hydrogenation. Intermediates, as well as methyl furan, are produced faster when starting with furfuryl alcohol as the reactant, rather than furfural, indicating that initial hydrogenation of furfural to furfuryl alcohol is slow. Catalyst recycling experiments over spent Ru/C catalyst show that, although furfural conversion does not decrease significantly, furfuryl alcohol yield increases at the expense of methyl furan. The initial catalytic activity and selectivity are regained completely after catalyst regeneration. We show evidence that the active phase of the catalyst involves Ru and RuOx.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
大幅提高文件上传限制,最高150M (2024-4-1)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
刚刚
科研通AI2S应助Theone采纳,获得10
1秒前
Jonathan完成签到,获得积分10
2秒前
3秒前
dingth完成签到,获得积分10
3秒前
桐桐应助malistm采纳,获得10
3秒前
CodeCraft应助hushan53采纳,获得10
3秒前
甜甜的振家完成签到,获得积分10
4秒前
清萍红檀发布了新的文献求助10
4秒前
隐形曼青应助小鱼采纳,获得10
6秒前
CQ发布了新的文献求助10
7秒前
种草匠完成签到,获得积分10
7秒前
8秒前
DAJI发布了新的文献求助10
8秒前
chenyuns发布了新的文献求助10
9秒前
豌豆完成签到 ,获得积分10
9秒前
Dora完成签到,获得积分10
9秒前
NINI完成签到,获得积分20
9秒前
9秒前
9秒前
无限向东完成签到 ,获得积分10
10秒前
11秒前
昵称完成签到,获得积分10
11秒前
11秒前
毛豆爸爸应助梅良心采纳,获得10
12秒前
薰硝壤应助瓜洲采纳,获得100
13秒前
zzuzll发布了新的文献求助10
13秒前
汉堡包应助dingth采纳,获得10
14秒前
14秒前
影子完成签到,获得积分10
14秒前
Akim应助追寻的城采纳,获得10
14秒前
13完成签到,获得积分20
15秒前
16秒前
Dr终年完成签到,获得积分10
16秒前
16秒前
亭树发布了新的文献求助10
16秒前
xiaohuang发布了新的文献求助10
16秒前
hitchem完成签到,获得积分10
17秒前
18秒前
19秒前
高分求助中
Pharmacogenomics: Applications to Patient Care, Third Edition 1000
Studien zur Ideengeschichte der Gesetzgebung 1000
TM 5-855-1(Fundamentals of protective design for conventional weapons) 1000
Genera Insectorum: Mantodea, Fam. Mantidæ, Subfam. Hymenopodinæ (Classic Reprint) 800
Ethnicities: Media, Health, and Coping 700
Development of a new synthetic process for the synthesis of (S)-methadone and (S)- and (R)-isomethadone as NMDA receptor antagonists for the treatment of depression 500
A Dissection Guide & Atlas to the Rabbit 500
热门求助领域 (近24小时)
化学 医学 生物 材料科学 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 基因 遗传学 催化作用 物理化学 免疫学 量子力学 细胞生物学
热门帖子
关注 科研通微信公众号,转发送积分 3089386
求助须知:如何正确求助?哪些是违规求助? 2741586
关于积分的说明 7565941
捐赠科研通 2392093
什么是DOI,文献DOI怎么找? 1268497
科研通“疑难数据库(出版商)”最低求助积分说明 614069
版权声明 598692