Rh(III)‐Catalyzed [4+2] Cyclization of 2‐Aryl‐1H‐benzo[d]imidazoles with Maleimides via C‐H Activation

Abstract A rhodium‐catalyzed formal [4+2]‐cyclization of 2‐aryl‐1 H ‐benzo[ d ]imidazoles with maleimides through C−H bond activation process is described here. Such an approach enables selectively construct a series of functionalized cis ‐dihydro‐benzimidazo[2,1‐ a ]isoquinolines. The reaction features a broad substrate scope with respect to both coupling components, and the desired products were obtained with up to 85 % yields.