Abstract A novel heap leaching method was investigated for selective removal of chromium (Cr) and vanadium (V) from ferrochromium (FeCr) and stainless steel (SS) slags. In particular, alkaline oxidative heap leaching was simulated on lab-scale by batch and column leaching tests. The results show a selective leaching of Cr (11–19%) and V (7.0–7.5%) after 64 days of column leaching, with a very low dissolution ( 2 ).